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Nickel distribution and isotopic fractionation in a Brazilian lateritic regolith: coupling Ni isotopes and Ni K-edge XANES. ArchiMer
Ratie, G.; Garnier, J.; Calmels, D.; Vantelon, D.; Guimaraes, E.; Monvoisin, G.; Nouet, J.; Ponzevera, Emmanuel; Quantin, C..
Ultramafic (UM) rocks are known to be nickel (Ni) rich and to weather quickly, which makes them a good candidate to look at the Ni isotope systematics during weathering processes at the Earth’s surface. The present study aims at identifying the Ni solid speciation and discussing the weathering processes that produce Ni isotope fractionation in two deep laterite profiles under tropical conditions (Barro Alto, Goiás State, Brazil). While phyllosilicates and to a lower extent goethite are the main Ni-bearing phases in the saprolitic part of the profile, iron (Fe) oxides dominate the Ni budget in the lateritic unit. Nickel isotopic composition (δ60Ni values) has been measured in each unit of the regolith, i.e., rock, saprock, saprolite and laterite (n=52)....
Tipo: Text Palavras-chave: Nickel cycle; Lateritic regolith; Nickel isotopes; XANES; Ultramafic environment; Weathering.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00436/54712/56149.pdf
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Nickel isotope fractionation during tropical weathering of ultramafic rocks ArchiMer
Ratie, G.; Jouvin, D.; Garnier, Julien; Rouxel, Olivier; Miska, S.; Guimaraes, E.; Cruz Vieira, L.; Sivry, Y.; Zelano, I.; Montarges-pelletier, E.; Thil, F.; Quantin, C..
Although Ni isotopes have been shown to be significantly fractionated in terrestrial samples, their use in continental environmental studies has not yet been evaluated. The present study focuses on an ultramafic (UM) massif (Barro Alto, Goias, Brazil) because such areas are naturally rich in Ni. We present developed lateritic weathering profiles. The goal of the study is to evaluate the potential of using Ni isotopes in environmental continental studies by combining its isotopic signature with mineralogy, in order to better understand the geochemical cycling of Ni in UM settings during weathering. As such, Ni isotope values were measured in samples from the Barro Alto UM complex in the main stages of the lateritic weathering profile of UM rocks, including...
Tipo: Text Palavras-chave: Nickel; Isotope; Weathering; Mineralogy; Soil.
Ano: 2015 URL: https://archimer.ifremer.fr/doc/00254/36553/35098.pdf
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